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C. Robert (Bob) Lucas, Professor Emeritus

REFEREED PUBLICATIONS

REFEREED PUBLICATIONS

1. C.R. Lucas and M.E. Peach, Metal Derivatives of Pentachlorothiophenol, Inorg. and Nucl. Chem. Letters, 5, 73 (1969).

2. C.R. Lucas and M.E. Peach, Reactions of Pentachlorothiophenol. I. Preparation of Some Simple Metallic and Non-Metallic Derivatives, Can. J. Chem., 48, 1869 (1970).

3. C.R. Lucas, M.E. Peach and K.K. Ramaswamy, Some Reactions of M(SC6Cl5)2, M = Ni, Pd, Pt, J. Inorg. Nucl. Chem., 34, 3267 (1972).

4. C.R. Lucas and M.L.H. Green, Some d1 bis-(π-cyclopentadienyltitanium Complexes with Nitrogen or Phosphorus Ligands, J. Chem. Soc., Dalton Trans., 1000 (1972).

5. C.R. Lucas and M.L.H. Green, A Convenient Route to Three-Valent Bis-π-cyclopentadienyl Niobium Hydrides and Related Derivatives, Chem. Comm., 1005 (1972).

6. C.R. Lucas, M.L.H. Green, R.A. Forder and C.K. Prout, Crystal and Molecular Structure of Triscyclopentadienyltitanium: the Cyclopentadienyl Group as a Two-centre Three-electron Ligand, Chem. Comm., 97 (1973).

7. M.L.H. Green and C.R. Lucas, Some d1-π-cyclopentadienyltitanium Compounds with Halogen, Alkyl and Phosphine Ligands, J. Organomet. Chem., 73, 259 (1974).

8. C.R. Lucas and M.L.H. Green, Some d1 (η-cyclopentadienyl Complexes of Titanium, Inorg. Synth., XVI, 237 (1976).

9. C.R. Lucas, Bis(η-cyclopentadienyl)niobium Complexes, Inorg. Synth., XVI, 107 (1976).

10. C.R. Lucas, Bis(η-cyclopentadienyl)(tetrahydroborato)titanium, Inorg. Synth., XVII, 91 (1977).

11. C.R. Lucas, Reactions of Sulfinyl Carbanions with Organometallic Compounds, J. Organometal. Chem., 236, 281 (1982).

12. C.R. Lucas, Tungsten Carbonyl Complexes of Main Group IV Organometallic Sulfides, Can. J. Chem., 61, 1096 (1983).

13. C.R. Lucas, Thioether Complexes of Tungsten Hexacarbonyl, Can. J. Chem., 64, 1758 (1986).

14. C.R. Lucas and K.A. Walsh, Organometallic Chemistry of Molybdenum, J. Chem. Educ., 64, 265 (1987).

15. C.R. Lucas, M.J. Newlands, E. Gabe and F.L. Lee, The Synthesis, Crystal and Molecular Structures of Triphenyl(phenylthio)silane, Ph3SiSPh and bis(μ-thiophenolato)-bis[tetracarbonyl tungsten(I)], [W(CO)4SPh]2, Can. J. Chem., 65, 898 (1987).

16. C.R. Lucas, E.J. Gabe and F.L. Lee, Cyclopentadienyl-metal Bond Cleavage and Stereospecific Bromination. The Structure of (η-C5H5)2Ti(OOCPh)2 and its Reactions with Bromine, Can. J. Chem., 66, 429 (1988).

17. C.R. Lucas, Liu Shuang, M.J. Newlands, E.J. Gabe and J.P. Charland, Thiophenophane-Metal Complexes I. Preparation, X-ray Structure and Cyclic Voltammetry of 2,5,8-trithia[9](2,5)thiophenophane, L, and its Metal Complex Cation bis(2,5,8-trithia[9](2,5)thiophenophane-S2S3)copper(I), [CuL2]+, Can. J. Chem., 66, 1506 (1988).

18. C.R. Lucas, Shuang Liu, M.J. Newlands, J.P. Charland and E.J. Gabe, Thiophenophane Metal Complexes II. Preparation, Structure and Properties of Binuclear Copper(II) Complexes and of 2,5,9,12-tetrathia[13](2,5)thiophenophane. Evidence for S-Coordinated Thiophene, Can. J. Chem. 67, 639 (1989).

19. S. Liu and C.R. Lucas, Synthesis and Characterization of Novel Homoleptic Polythia-Crown-Ether-Containing Thiophene Rings, Shandong Yike Daxue Xuebao, 27, 55-58 (1989).

20. C.R. Lucas, S. Liu and L.K. Thompson, Magneto-structural Correlations and ESR Spectra of Dinuclear Copper(II) Complexes of Thiophenophane Ligands Containing Thioether Donor Atoms, Inorg. Chem., 29, 85 (1990).

21. C.R. Lucas, S. Liu, M.J. Newlands, J.P. Charland and E.J. Gabe, Thiophenophane Metal Complexes III. Preparation, X-ray Structure and Properties of 2,5,8,11-tetrathia[12](2,5)thiophenophane, L, and [Ag2L2]2+ its Dinuclear Silver Complex Cation, Can. J. Chem., 68, 644 (1990).

22. C.R. Lucas, S. Liu, M.J. Newlands and E.J. Gabe, X-ray Structural and NMR Study of Rigidity in Open Chain and Macrocyclic Thioether Complexes, Can. J. Chem., 68, 1357 (1990).

23. S. Liu, C.R. Lucas, M.J. Newlands and J.P. Charland, Thiophenophane Metal Complexes 4. Structural and Nmr Study of a 1,4-Fluxional Pivot About a Pd-S (thiophene) Bond, Inorg. Chem., 29, 4380 (1990).

24. C.R. Lucas, Dichlorobis(η5-cyclopentadienyl)niobium(IV) Complexes, Inorg. Synth., XXVIII, 267 (1990), (invited contribution).

25. H. Wu and C.R. Lucas, Stereochemical Non-rigidity in Thioether Complexes, Inorg. Chem., 31, 2354 (1992).

26. S. Liu, C.R. Lucas, R.C. Hynes, and J.P. Charland, Structure Effects in Copper Coordination Compounds of Ligands with Thioether, Aromatic Nitrogen and Ether Donors, Can. J. Chem., 70, 1773 (1992).

27. H. Wu and C.R. Lucas, Solution Structures of Copper Coordination Compounds Containing Ligands with Ether or Thioether Donors, Inorg. Chem., 32, 526 (1993).

28. B. Adhikary, S. Liu and C.R. Lucas, Comparative Studies of Mononuclear Ni(II) Complexes with N2Sx (x = 2-4) Ligands, Inorg. Chem., 32, 5957 (1993).

29. S. Liu and C.R. Lucas, Unusual Properties of Metal Complexes Involving Acyclic Polydentate Thioether Ligands. Copper, Nickel and Palladium Complexes of 3,6,9,12,15-pentathiaheptadecane, J. Chem. Soc., Dalton Trans., 185 (1994).

30. B. Adhikary and C.R. Lucas, Copper(II) Complexes of N2S3 Ligands Involving Aromatic Nitrogen and Thioether Donors and Having High Redox Potentials, Inorg. Chem., 33, 1376 (1994).

31. C.R. Lucas and S. Liu, Macrocyclic Thioether-esters and Thioether-thioesters and Their Palladium, Platinum and Silver Complexes, Inorg. Chim. Acta, 230, 133 (1995).

32. C.R. Lucas, S. Liu and J.N. Bridson, Preparations for 1,4,7,11,14,17-hexathiacycloeicosane, 1,4,7-trithiecan-9-ol, 1,11-dioxa-4,8,14,18-tetrathiacycloeicosane, 1-oxa-4,8-dithiacyclodecane and Some Complexes of Iron, Cobalt, Nickel and Palladium, Can. J. Chem., 73, 1023 (1995), (solicited contribution).

33. C.R. Lucas and S. Liu, Thiophenophane Metal Complexes. IV. Effects from Ligand Changes Outside the Coordination Sphere, Can. J. Chem., 74, 2340 (1996), (solicited contribution).

34. B. Adhikary, S. Liu and C.R. Lucas, Complexes of Cobalt, Nickel, Palladium and Silver with N2Sx (x = 3 or 4) Ligands Involving Aromatic Nitrogen and Thioether Donors, Inorg. Chim Acta, 261, 15-21 (1997).

35. C.R. Lucas and S. Liu, X-ray Structure and Variable Temperature Magnetic Properties of a Zigzag (Cu-Cl)n Chain, Inorg. Chem., 36, 4336-4340 (1997).

36. C.R. Lucas, W. Liang, D.O. Miller and J.N. Bridson, Metal Complexes of 1-oxa-4,7-dithiacyclononane, Inorg. Chem., 36, 4508-4513 (1997).

37. W. Liang, S. Liu, C.R. Lucas and D.O. Miller, Silver, Copper and Nickel Complexes of 1-oxa-4,7-dithiacyclononane and 1-oxa-4,8-dithiacyclodecane, Polyhedron, 17, 1323-1328 (1998).

38. S.K. Chattopadhyay, K. Mitra, S. Biswas, C.R. Lucas, D.O. Miller and B. Adhikary, Studies on Mn(II) and Mn(IV) Complexes of an Unsymmetrical Bidentate Donor, N(4-Chlorophenyl)-Pyridine-2-Aldimine (ClL): Crystal Structure of [Mn(ClL)2(NCS)2], J. Coord. Chem., 55, 1409-1418 (2002).

39. B. Adhikary, K. Mitra, S. Biswas, C.R. Lucas and S.K. Chattopadhyay, Synthesis of Manganese Complexes With Different Bidentate Ligands, Indian J. Chem., Sec. A, 100-101 (2002).

40. S.K. Chattopadhyay, K. Mitra, C.R. Lucas, D.O. Miller and B. Adhikary, Synthesis of Two Novel Benzimidazole Derivatives Mediated by Mn(III), Indian J. Chem., Sec. A, 101-102 (2002).

41. S.K. Chattopadhyay, K. Mitra, S. Biswas, C.R. Lucas and B. Adhikary, Synthesis of Four Novel Benzimidazole Derivatives Mediated by Manganous Acetate - Permanganate Mixture, J. Chem. Res., J. Chem. Res. (S), 9, 562-563 (2003).

42. S. Biswas, K. Mitra, C.H. Schwalbe, C.R. Lucas, S.K. Chattopadhyay and B. Adhikary. Synthesis and Characterization of Some Mn(II) and Mn(III) Complexes of N,N-o-phenylenebis(salicylideneimine)(LH2) and N,N-o-phenylenebis(5-bromosalicylideneimine)(LH2). Crystal structures of [Mn(L)(H2O)(ClO4)], [Mn(L)(NCS)] and an Infinite Linear Chain of [Mn(L)(OAc)], Inorg. Chim. Acta, 358, 2473-2481 (2005).

43. K. Mitra, S. Biswas, S.K. Chattopadhyay, B. Adhikary and C.R. Lucas, Synthesis, Spectroscopy and Redox Properties of Mononuclear Manganese(II) and Manganese(IV) Complexes with N-(aryl)-pyridine-2-aldimine (L) and its Amide Derivatives. X-ray Structural Characterization of [Mn(MeL)2(NCS)2] (MeL = N-(4-methylphenyl)-pyridine-2-aldimine), Transition Met. Chem., 30, 185-190 (2005).

44. S. Biswas, K. Mitra, S.K. Chattopadhyay, B. Adhikary and C.R. Lucas, Mononuclear Manganese(II) and Manganese(III) Complexes of N2O Donors Involving Amine and Phenolate Ligands: Absorption Spectra, Electrochemistry and Crystal Structure of [Mn(L3)2](ClO4), Transition Met. Chem., 30, 393-398 (2005).

45. S. Biswas, K. Mitra, B. Adhikary and C.R. Lucas, Studies on Binuclear Hydroxo/Carbonato-Bridged Manganese(III) Complexes and a Mononuclear Manganese(III) Complex Involving Salen Type Ligands, Transition Met. Chem., 30, 586-592 (2005).

46. K. Mitra, S. Biswas, C.Robert Lucas and B. Adhikary, Manganese(III) Complexes of N2O2 Donor 5-Bromosalicylideneimine Ligands: Combined Effects of Electron Withdrawing Substitutents and Chelate Ring Size Variations on Electrochemical Properties, Inorg. Chim. Acta, 359, 1997-2003 (2006).

47. K. Mitra, D. Mishra, S. Biswas, C.R. Lucas and B. Adhikary, Binuclear Manganese(III) Complexes with Carboxylate Bridges: Synthesis, Structure, Electrochemistry and Magnetic Properties, Polyhedron, 25, 1681-1688 (2006).

48. K. Mitra, S. Biswas, S.K. Chattopadhyay, C.R. Lucas and B. Adhikary, Synthesis and X-ray Crystal Structures of Two Luminescent Imidazopyridinium Derivatives from the Corresponding N-(aryl)-pyridine-2-aldimines, J. Chem Crystallogr., 37, 567-571 (2007).

49. M. Nayak, S. Hazra, P. Lemoine, R. Koner, C.R. Lucas and S. Mohanta, Self-Assembled [2x1+1x2] Heterotetranuclear CuII3MnII/CuII3CoII and [2x2+1x3] Heptanuclear CuII7 Compounds Derived from N,N-o-phenylenebis(3-ethoxysalicylaldimine): Structures and Magnetic Properties, Polyhedron, 27, 1201-1213 (2008).

50. S.S. Tandon and C.R. Lucas, Metal-Induced Facile Synthesis of a Tricyclic System: 10-methyl-12-thia-2,9-diaza-tricyclo[8.3.1.03,8]tetradeca-3,5,7-triene-1-carbonitrile. Formation of an Intramolecular Carbon-Carbon Bond, Can. J. Chem., 86, 912-917 (2008).

51. S. Majumder, R. Koner, P. Lemoine, M. Nayak, M. Ghosh, S. Hazra, C.R. Lucas and S. Mohanta, Role of Coordinated Water and Hydrogen-Bonding Interactions in Stabilizing Monophenoxido-Bridged Triangular CuIIMIICuII Compounds (M = Cu, Co, Ni or Fe) Derived from N,N-Ethylenebis(3-methoxysalicylaldimine): Syntheses, Structures and Magnetic Properties, Eur. J. Inorg. Chem., 3447-3457 (2009).

52. R Koner, S. Hazra, M. Fleck, A. Jana, C.R. Lucas and S. Mohanta, Magnetic and Electrochemical Properties of a Heterobridged μ-Phenoxo-μ1,1-Azide Dinickel(II) Compound: A Unique Example Demonstrating the Bridge Distance Dependency of Exchange Integral, Eur. J. Inorg. Chem., 4982-4988 (2009).

53. S. Biswas, A Dutta, K. Mitra, M-C. Dul, C.R. Lucas and B. Adhikary, Synthesis, Characterization, Electrochemical and Magnetic Studies on Manganese(III) Complexes Involving Bridging Carboxylates: Crystal Structure of [Mn2L2(ClCH2COO)](ClO4), Inorg. Chim. Acta, 377, 56-61 (2011).

54. C.R. Lucas, J.M.D. Byrne, J.L. Collins, L.N. Dawe and D.O. Miller, Copper(II) Complexes of Open-Chain Thioether Ligands Terminated by Salicylaldimine Functionality, Can. J. Chem., 89, 1190-1201 (2011).

55. C.R. Lucas, J.M.D. Byrne, J.L. Collins, L.N. Dawe and D.O. Miller, Cobalt and Nickel Complexes of Open-Chain Thioether Ligands Terminated by Salicylaldimine Functionality, Can. J. Chem., 89, 1174-1189 (2011).

56. S. Majumder, M. Fleck, C.R. Lucas and S. Mohanta, A New Tetraiminodiphenol Macrocyclic Ligand and its Two Dicopper(II) Complexes: Syntheses, Crystal Structures, Electrochemistry and Magnetochemistry, J. Mol. Struct., 1020, 127-133 (2012).

57. A.K. Dutta, S.K. Maji, S. Dutta, C.R. Lucas and B. Adhikary, Syntheses, Crystal Structure, Spectroscopic, Redox, and Magnetic Properties of Oxo- and Carboxylato-Bridged Polynuclear Iron(III) Complexes with Phenolate- and Pyridine-Substituted Benzimidazole Ligands, Polyhedron, 44, 34-43, (2012).

58. A.K. Dutta, S.K. Maji, S. Dutta, C.R. Lucas and B. Adhikary, Synthesis, Structural and Magnetic Properties of Oxo-, Chloroacetato-Bridged Iron(III) Complex, J. Mol. Struct., 1029, 68-74, (2012).

59. A. Biswas, L.Mandal, S. Mondal, C.R. Lucas and S. Mohanta, More Surprising Differences Between Two Closely Similar Compartmental Ligand Families and Another Dinuclear Synthon to Stabilize Dinuclear-Mononuclear Cocrystals, CrystEngComm., 15, 5888-5897 (2013).

60. L.N. Dawe, L. Penney, D.A. Black, D.O. Miller and C.R. Lucas, cis-dichloro-(3, 6, 9-trithiabicyclo[9.3.1]pentadecane-2S3,S6)-palladium(II) acetonitrile 0.8-solvate, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 69(7), 727-729 (2013).

61. L.N. Dawe, B. Adhikary, J.L. Collins and C.R. Lucas, Bis{[2,2-(5,8,11-trithia-2,14-diazapentadeca-1,14-diene-1,15-diyl)diphenolato]-palladium(II)} acetonitrile monosolvate, Acta Crystallogr., Sect. E: Struct. Rep. Online, 69(7), m360-m361 (2013).

62. A.K. Dutta, S. Biswas, S. Dutta, L.N. Dawe, C.R. Lucas and B. Adhikary, Syntheses, structural, spectroscopic and magnetic properties of polynuclear Fe(III) complexes containing N and O donor ligands, Inorg. Chim Acta, 444, 141-149 (2016).

63. A.K. Dutta, S. Samanta, S. Dutta, C.R Lucas, L.N. Dawe, P. Biswas, B. Adhikary, Iron(III) complexes of 2-(1H-benzo[d]imidazol-2-yl)phenol and acetate or nitrate as catalysts for epoxidation of olefins with hydrogen peroxide, J. Mol. Struct., 1115, 207-213 (2016).